Study on separation of ReO4 −, a substitute for TcO4 −, using functional ionic liquid impregnated extraction chromatography resins-Reference-Cited by-同舟云学术

Study on separation of ReO₄ ⁻, a substitute for TcO₄ ⁻, using functional ionic liquid impregnated extraction chromatography resins

Published:2024-09-13 Issue: Volume: Page:
ISSN:0033-8230
Container-title:Radiochimica Acta
language:en
Short-container-title:

Author:

Liu Meiying¹,Zhi Xupeng¹,Liu Peng¹,Li Xiaomin¹,Chen Xinlong¹,Liu Bin¹²,Shen Yinglin¹^ORCID

Affiliation:

1. School of Nuclear Science and Technology , Lanzhou University , Lanzhou 730000 , China

2. School of Stomatology , Lanzhou University , Lanzhou 730000 , China

Abstract

Abstract 99Tc has a long half-life, high fission yield, and good environmental mobility, posing a significant threat to the environment and human health. Therefore, removing technetium from radioactive wastewater is a very important and urgent task. For laboratory safety reasons, ReO4 − is often used as a non-isotopic substitute for 99TcO4 −. From this point of view, the study of the separation behavior of Re in the aqueous phase can provide a reference value for the removal of 99Tc. Here, a new type of extraction chromatography resin was prepared by impregnating the functionalized ionic liquid into the macroporous resin, whose imidazolium cations modified by amide functional groups which can effectively capture ReO4 −/TcO4 − from simulated radioactive wastewater. The results show the resin has good adsorption performance and fast adsorption kinetics (the adsorption equilibrium is about 20 min). The adsorption mechanism was investigated using Fourier transform infrared (FT-IR) spectra and X-ray photoelectron spectroscopy (XPS). It shows that the adsorption process is an anion exchange between Cl− in the resin and ReO4 − in the solution.

Publisher

Walter de Gruyter GmbH

Link

https://www.degruyter.com/document/doi/10.1515/ract-2024-0290/pdf

Reference33 articles.

1. Suman, S. Hybrid Nuclear-Renewable Energy Systems: A Review. J. Cleaner Prod. 2018, 181, 166–177; https://doi.org/10.1016/j.jclepro.2018.01.262.

2. Hu, H.; Sun, L.; Gao, Y.; Wang, T.; Huang, Y.; Lv, C.; Zhang, Y. F.; Huang, Q.; Chen, X.; Wu, H. Synthesis of ZnO Nanoparticle-Anchored Biochar Composites for the Selective Removal of Perrhenate, a Surrogate for Pertechnetate, from Radioactive Effluents. J. Hazard. Mater. 2020, 387, 121670; https://doi.org/10.1016/j.jhazmat.2019.121670.

3. Banerjee, D.; Kim, D.; Schweiger, M. J.; Kruger, A. A.; Thallapally, P. K. ChemInform Abstract: Removal of TcO4‐ ions from Solution: Materials and Future Outlook. Chem. Soc. Rev. 2016, 45 (10), 2724–2739; https://doi.org/10.1039/c5cs00330j.

4. Zhu, L.; Sheng, D.; Xu, C.; Dai, X.; Silver, M. A.; Li, J.; Li, P.; Wang, Y.; Wang, Y.; Chen, L.; Xiao, C.; Chen, J.; Zhou, R.; Zhang, C.; Farha, O. K.; Chai, Z.; Albrecht-Schmitt, T. E.; Wang, S. Identifying the Recognition Site for Selective Trapping of (TcO4-)-Tc-99 in a Hydrolytically Stable and Radiation Resistant Cationic Metal-Organic Framework. J. Am. Chem. Soc. 2017, 139 (42), 14873–14876; https://doi.org/10.1021/jacs.7b08632.

5. Eagling, J.; Worsfold, P. J.; Blake, W. H.; Keith-Roach, M. J. Mobilization of Technetium from Reduced Sediments under Seawater Inundation and Intrusion Scenarios. ES&T 2012, 46 (21), 11798–11803; https://doi.org/10.1021/es3025935.