Extraction of some univalent and divalent cations into nitrobenzene in the presence of calcium ionophore I-Reference-Cited by-同舟云学术

Extraction of some univalent and divalent cations into nitrobenzene in the presence of calcium ionophore I

Published:2023-10-05 Issue:11 Volume:111 Page:839-844
ISSN:0033-8230
Container-title:Radiochimica Acta
language:en
Short-container-title:

Author:

Vaňura Petr¹^ORCID,Makrlík Emanuel²

Affiliation:

1. Department of Analytical Chemistry , University of Chemistry and Technology , Prague , Technická 5, 166 28 Prague 6 , Czech Republic

2. Faculty of Environmental Sciences , Czech University of Life Sciences , Prague , Kamýcká 129, 165 21 Prague 6 – Suchdol , Czech Republic

Abstract

Abstract The stability constants of the Calcium ionophore I (i.e., N,N´ – di[(11′- ethoxycarbonyl) undecyl] – N,N′,4,5 -tetramethyl – 3,6 – dioxaoctane diamide) complexes with Mn+ (Mn+ = Li+, H3O+, Na+, NH4 +, Ag+, K+, Rb+, Tl+, Cs+, Ca2+, Sr2+, Ba2+. Pb2+, Cu2+, Zn2+) in nitrobenzene saturated with water were determined by the extraction method. These constants were found to increase in the series of Cs+ < Rb+ < K+ < NH4 + < Na+ < Tl+ < H3O+ < Ag+ < Li+ and Ba2+ < Zn2+ < Sr2+ < Pb2+ < Cu2+< Ca2+.

Funder

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague

Czech Ministry of Education, Youth, and Sports

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/ract-2023-0128/pdf

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