The speciation of protactinium since its discovery: a nightmare or a path of resilience-Reference-Cited by-同舟云学术

The speciation of protactinium since its discovery: a nightmare or a path of resilience

Published:2022-04-21 Issue:6-9 Volume:110 Page:481-493
ISSN:0033-8230
Container-title:Radiochimica Acta
language:en
Short-container-title:

Author:

Le Naour Claire¹,Maloubier Melody¹,Aupiais Jean²

Affiliation:

1. Université Paris-Saclay, CNRS/IN2P3, IJCLab , 91405 Orsay , France

2. CEA, DAM, DIF , 91297 Arpajon , France

Abstract

Abstract This review concerns the speciation of protactinium in aqueous solution under its both oxidation states +IV and +V. Emphasis is placed on experimental data obtained at trace level but also in macroscopic amount leading to the determination of thermodynamic and structural data. Thus, the complexation of Pa(V) with mineral acids and organic acids, mainly polyaminocarboxylic acids (iminodiacetic acid [IDA], nitrilotriacetic acid [NTA], ethylenediaminetetraacetic acid [EDTA] and diethylenetriaminepentaacetic acid [DTPA]) are highlighted and compared. The review also includes the actual knowledge about the Pa(IV) aqueous chemistry pinpointing its spectroscopic features.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/ract-2021-1126/pdf

Reference114 articles.

1. Fajans, K. Die Stellung der Radioelemente im periodischen System. Phys. Z. 1913, 14, 136.

2. Russell, A. S. The periodic system and the radio-elements. Chem. News 1913, 107, 49.

3. Soddy, F. The radio-elements and the periodic law. Chem. News 1913, 107, 97; https://doi.org/10.1038/091057a0.

4. Fajans, K., Göhring, O. Über die komplexe Natur des UrX. Naturwissenschaften 1913, 14, 339; https://doi.org/10.1007/bf01495360.

5. Hahn, O., Meitner, L. Die Muttersubstanz des Actiniums, ein neues radio-aktives Element von langer Lebensdauer. Phys. Z. 1918, 19, 208.

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