Utilization of electron beam irradiated carboxymethyl cellulose/polyvinyl alcohol/banana peels composite film for remediation of dyes from wastewater

Abstract

Abstract In this work, polymeric composite films were fabricated utilizing stable, non-toxic, soluble, low-cost, good mechanical, and biocompatible polymers such as CMC and PVA with the waste of one of the most current fruits consumed worldwide banana peel waste (BP) as a filler. Sequences of carboxymethyl cellulose/polyvinyl alcohol/banana peel (CMC/PVA/BP) composite films with various amounts of BP utilizing eco-friendly technique (electron beam) (EB) irradiation were prepared to eliminate common hazardous organic pollutants such as methylene blue (MB) dye from its solutions. Physical characteristics like; swelling and gel % were examined. The chemical structure, thermal stability, and surface morphology were examined utilizing FT-IR, TGA, DSC, XRD, EDX, and SEM. Additionally, the UV/Vis spectroscopy study was investigated to study the impact of the various parameters such as irradiation, contact time, pH, temperature, adsorbent dosage, and initial concentration on removal efficiency % of MB dye onto the prepared composite films. The adsorption process fitted with the Langmuir model, pseudo-second-order kinetic model, endothermic, favorable, and spontaneous. The adsorption capacity of MB dye onto the CMC/PVA/BP composite film was 19.6 mg/g at the optimum conditions: irradiation dose = 20 kGy, contact time = 120 min, pH = 10, temperature = 25 °C, adsorbent dosage = 0.1 g and initial conc. = 10 mg/L.