Natural and anthropogenic radionuclides in karstic coastal area (Kaštela Bay, Adriatic Sea, Croatia) exposed to anthropogenic activities: distribution, sources, and influencing factors

Abstract

Abstract 40K, 226Ra, 232Th, 238U, and 137Cs massic activities were determined by gamma-spectrometry in limestones, marls, stream sediments, and soils of Kaštela Bay (Adriatic Sea, Croatia) coastal area. Their distribution, sources and potential influencing factors were studied. The lowest 40K, 226Ra, 232Th, and 238U massic activities were determined in limestones and the highest in soils, with the following median values, respectively: 7.2, 14, 0.8, and 5.3 Bq/kg in limestones and 518, 72, 71, and 31 Bq/kg in soils. All four radionuclides were of natural origin and reflected background values of the karstic area influenced by flysch/marl and terra rossa soil. Local TENORM disposal site did not influence the study area, but it will be needed to study its potential influence on marine sediments. Strong disequilibrium between 226Ra and 238U was found in limestones s.l. and soils, but not in marls and only moderately in stream sediments. This implies that limestones are more susceptible to selective 238U leaching than marls, and soils more than stream sediments. 137Cs was the only radionuclide of anthropogenic origin, with a global source only. It was detected in stream sediments and soils with median values of 5.4 and 31 Bq/kg, respectively. 137Cs distribution was more heterogeneous in stream sediments than in soils, but soils generally presented higher activities. Soil is considered the most important reservoir of 137Cs and its potential source.