Lignin reinforced, water resistant, and biodegradable cassava starch/PBAT sandwich composite pieces

Abstract

Abstract Following the stipulation to replace nondegradable plastics with biodegradable materials in China, cost-effective and water-resistant packaging materials have become increasingly necessary. In this work, lignin reinforced thermoplastic cassava starch (TPS) pieces were prepared by filling glycerol and lignin powder into starch via a melt blending process and then being pressed into thin pieces. A mechanical properties test showed that following the addition of 3 wt% lignin, the tensile strength of the TPS piece was improved to 16.15 MPa from 3.71 MPa of the original TPS piece. The porous structures of the lignin powder tie the TPS macromolecular chains, induce higher crystallization, and thus provide higher tensile strength and lower elongation at break. After sandwiching two pieces of poly (butylene adipateco-terephthalate) (PBAT)/peanut shell powder composite thin film to each side of the TPS piece, the PBAT/TPS/PBAT sandwich gains excellent water resistance properties. However, as soon as the sandwich piece is cut into smaller ones, they absorb water quickly, implying such pieces can be biodegraded rapidly. These characteristics make it especially suitable for use in the preparation of cabinet waste bags, which are generally stirred into organic fertilizer with the cabinet waste. Slow degradation may negatively affect soil health and farm production.