Pyrolysis and combustion of polystyrene composites based on graphene oxide functionalized with 3-(methacryloyloxy)-propyltrimethoxysilane

Author:

Anghel Ion1,Lisa Gabriela2,Şofran Ioana-Emilia1,Mitroi-Symeonidis Flavia-Corina34,Rusu Mihai Marius56,Baia Monica78,Baia Lucian579,Magyari Klára5,Danciu Virginia59,Cotet Liviu Cosmin95,Stroe Malvina6,Baibarac Mihaela6

Affiliation:

1. Police Academy “Alexandru Ioan Cuza”, Fire Officers Faculty , Str. Morarilor 3, Sector 2 , 022451 Bucharest , Romania

2. Department of Chemical Engineering , Faculty of Chemical Engineering and Environmental Protection “Cristofor Simionescu”, Gheorghe Asachi Technical University of Iasi , Bd. Mangeron 73 , 700050 Iasi , Romania

3. Police Academy “Alexandru Ioan Cuza” , Fire Officers Faculty , Str. Morarilor 3, Sector 2 , 022451 Bucharest , Romania

4. Department of Applied Mathematics , Academy of Economic Studies , Calea Dorobanti 15-17, sector 1 , 010552 Bucharest , Romania

5. Institute of Interdisciplinary Research in Bio-Nano-Sciences , Center of Nanostructured Materials and Bio-Nano-Interfaces, Babes-Bolyai University , T. Laurean 42 , 400271 Cluj-Napoca , Romania

6. Laboratory of Optical Processes in Nanostructure Materials, National Institute of Materials Physics , Atomistilor str. 405 A , 77125 Bucharest , Romania

7. Institute for Research-Development-Innovation in Applied Natural Sciences , Advanced Materials and Applied Technologies Laboratory, Babes-Bolyai University , Fantanele str. 30 , 400294 Cluj-Napoca , Romania

8. Faculty of Physics, Babes-Bolyai University , M. Kogalniceanu str. 1 , 400048 Cluj-Napoca , Romania

9. Department of Chemical Engineering , Faculty of Chemistry and Chemical Engineering, Babes-Bolyai University , Arany Janos str. 11 , 400028 Cluj-Napoca , Romania

Abstract

Abstract In this study, polystyrene composites (PS–GOf) with variable concentration (0.5; 1; 2; 3; 4; and 5 wt%) of GOf were obtained through the in-situ polymerisation of the styrene in the presence of benzoyl peroxide and graphene oxide(GO) functionalized with 3-(methacryloyloxy)-propyltrimethoxysilane(γ-MPTS). For determining the morphological and structural particularities of polymeric composites transmission electron microscopy (TEM) measurements were performed. The influence of functionalized GO on thermal and combustion properties of polystyrene (PS)-based composite materials was determined through several methods: Thermogravimetry (TGA); derived thermogravimetry (DTG); microscale combustion calorimetry analysis (MCC); and chemical kinetic studies through TGA and MCC determinations at similar heating rates.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Polymers and Plastics,General Chemical Engineering

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