Heat distortion temperature of PPS/PC blend, PPS/PC nanocomposite and PPS/PC/GF hybrid nanocomposite

Abstract

Abstract The polyphenylene sulfide (PPS) blended with polycarbonate (PC), reinforced glass fiber (GF) and nanometer calcium carbonate (nano-CaCO3) filled PPS ternary composite, as well as the PPS/PC/GF/nano-CaCO3 hybrid composite, were prepared by means of a twin-screw extruder, and the heat distortion temperature (Td) of these materials was measured to identify the influence of the PC and nano-CaCO3 content on the heatproof properties. The Td values for the PPS/PC blend were lower than that of the neat PPS, when the PC weight fraction (φPC) was less than 20%, and increased with increase in φPC. The Td values for the PPS/GF/nano-CaCO3 ternary composite, on which the particle surface was treated with a titanate coupler, were higher than that of the composite with the particle surface treated with a stearate coupler. When the nano-CaCO3 weight fraction (φf) was less than 6%, the Td values for the PPS/PC/GF/nano-CaCO3 hybrid composites increased with increasing φf; at greater than the maximum of 6%, Td decreased. There was a certain synergistic effect of the GF and nano-CaCO3 on the heatproof properties in the PPS/PC composite.