Mechanical and flammability properties of a polyamide 6,6 nanocomposite for nonstructural marine engine components

Author:

Cozzarini Luca1,Benedetti Elena2,Piras Alessandro3,Terenzi Andrea3,Pricl Sabrina14,Schmid Chiara1

Affiliation:

1. Department of Engineering and Architecture , University of Trieste , Via Valerio 10 , 34127 Trieste , Italy

2. AEP Polymers , Area Science Park , Ed. Q1, SS 14 Km 163.5 , Basovizza , Trieste , Italy

3. Nanto Protective Coating , Via Monte Grappa 5 , Venezia , Italy

4. and Department of General Biophysics , Faculty of Biology and Environmental Protection, University of Lodz , 141/143 Pomorska St , 90-236 Lodz , Poland

Abstract

Abstract The actual replacement of traditional metallic components with plastic-based materials in the marine sector is currently extremely limited, mainly due to mechanical requirements and flammability issues. In this work, a fiberglass-reinforced polyamide 6,6 matrix, loaded with innovative flame retardants based on nanosized organoclays has been evaluated as a replacement for aluminum in a marine engine cover. Experimental data were acquired to assess the mechanical performances and flammability properties of this novel polymer nanocomposite in comparison with those of a commercial sample based on the same polymeric matrix loaded with traditional flame retardants. The results showed that then use of nanoclays in place of standard flame retardants increased the mechanical properties of the polymer nanocomposite at all tested temperatures (22% of modulus increase at 20 °C, 93% at 110 °C), concomitantly meeting the minimum nonflammability requirements (self-extinguishing, without dropping of flammable material).

Funder

Regione Autonoma Friuli Venezia Giulia

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Polymers and Plastics,General Chemical Engineering

Reference29 articles.

1. Consolidated Text of the International Convention for Safety of Life at Sea; International Maritime Organization, 1974.

2. International Code for Application of Fire Test Procedures (FTP Code); International Maritime Organization, 2010.

3. Standard for Tests for Flammability of Plastic Materials for Parts in Devices and Appliances (UL-94) Underwrites Laboratories Thermoplastic Testing Center; Underwriters Laboratories Inc., 2013.

4. Graham-Jones, J., Summerscale, J. Marine Applications of Advanced Fibre-Reinforced Composites, 1st ed.; Woodhead Publishing: Sawston, Cambridge, UK, 2015.

5. Vaidya, U. K., Chawla, K. K. Processing of fibre reinforced thermoplastic composites. Int. Mater. Rev. 2008, 53, 185–218; https://doi.org/10.1179/174328008X325223.

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