Thermal stability of xanthan gum biopolymer and its application in salt-tolerant bentonite water-based mud

Author:

Zou Zhifei1,Zhao Qingcheng1,Wang Qingying1,Zhou Fengshan1

Affiliation:

1. Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials , School of Materials Science and Technology, China University of Geosciences , Xueyuan Road, Haidian District , Beijing 100083 , PR China

Abstract

Abstract Xanthan gum from Xanthomona campestris (XC) is a chain-like polysaccharide biopolymer with good salt tolerance. The temperature resistance of XC seriously affects its application in drilling fluids. Results have shown that when the temperature of the XC solution rose to 120°C, after several hours the shear stress of the XC solution was almost 0 mPa · s at different shear rates. In this study, the molecular structure of XC was enhanced by crosslinking with chromic oxalate and borax and then adding sodium sulfite to further enhance the temperature resistance of the gum. Selected materials such as MgO, layered double-hydroxide, attapulgite, and asbestos fiber were added as shearing resistance reagents. Through continuous experimentation, the amounts of the reagents were optimized. After 120°C aging test, the drilling fluids of modified XC (MXC) could still maintain good rheological properties and low fluid loss. The application in China Dagang oilfield indicated that 0.019 w/v% MXC could improve the yield point from 6.5 to 8 Pa. MXC could also be used in bentonite to prepare salt-tolerant bentonite, which was successfully used in offshore exploration and construction engineering.

Funder

National Science and Technology Major Projects of China

Key Science and Technology Projects of Sinopec Group

Central Universities

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Polymers and Plastics,General Chemical Engineering

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