Shear Viscosity of the Homologous Series of wCHBT (n = 0 ÷ f 12) in the Isotropic and Nematic Phases

Author:

Jadżyn J.1,Dąbrowski R.2,Glumiak K.3,Czechowski G.3

Affiliation:

1. 1Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland

2. 2Institue of Chemistry, Military University of Technology, Kaliskiego 2, 01-489 Warsaw, Poland

3. 3Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznan, Poland

Abstract

Abstract The paper presents results of shear viscosity measurements performed on nematogenic 4-(trans-4'-n-alkylcyclohexyl)isothiocyanatobenzenes (CnH 2n + 1-CyHx-Ph-N=C=S, /nCHBT) in the isotropic (n = 0 ÷ 12) and nematic (« = 4 ÷ 12) phases. The viscosity measured in the nematic phase is, due to the flow alignment phenomenon, close to the Migsowicz T? 2 viscosity coefficient. An odd-even effect in the n dependence of the viscosity-activation energy is observed both in the nematic and isotropic phases of nCHBT.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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