Specific Heat and Nuclear Quadrupole Resonance Study of Thiourea-Hexachloroethane Inclusion Compound

Author:

Chekhova G. N.1,Goren S. D.2,Krieger Ju. H.1,Linsky D.3,Lusternik V.3,Panich A. M.2,Semenov A. R.1,Voronel A.3

Affiliation:

1. 1Institute of Inorganic Chemistry, Russian Academy of Sciences, Novosibirsk 630090, Russia

2. 2Department of Physics, Ben-Gurion University of the Negev, P.O. Box 653, Be'er Sheva 84105, Israel

3. 3R.&B. Sackler School of Physics and Astronomy, Faculty of Exact Sciences, Tel-Aviv University, Ramat-Aviv, 69978, Tel-Aviv, Israel

Abstract

Specific heat and 35Cl nuclear quadrupole resonance (NQR) measurements of the channel thio-urea-hexachloroethane inclusion compound are presented. Experimental NQR data confirm the results of atom-atom potential calculations that the guest sublattice comprises two types of nearly commensurate finite molecular chains, having different structure and separated by domain walls. Specific heat measurements show phase transition near 96 K.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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