Light harvester band gap engineering in excitonic solar cells: A case study on semiconducting quantum dots sensitized rainbow solar cells

Abstract

Abstract A systematic study on the fabrication of quantum dots sensitized solar cells (QDSSCs) exploiting hybrid networks of semiconducting light harvesters is presented, which shows how the engineering of band gaps of the device components by a very simple technique allows improving the solar energy conversion performances. Panchromatic devices are fabricated and tested, and correspondent functional parameters analyzed in order to highlight both advantages and drawbacks of the most common (CdS, CdSe, PbS) quantum dots applied for light collection in QDSSCs. Judicious engineering of the light harvester layer is demonstrated as a simple and powerful strategy for boosting device performances, through the management of light collection in a rather broad range of solar spectrum and photogenerated charges injection and collection.