Generation of singlet oxygen (1O2) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents-Reference-Cited by-同舟云学术

Generation of singlet oxygen (1O2) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents

Published:2014-06-18 Issue:6 Volume:86 Page:945-952
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:
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Author:

Kalay Erbay¹,Kılıç Hamdullah¹,Catir Mustafa²,Cakici Murat¹,Kazaz Cavit¹

Affiliation:

1. 1Faculty of Science, Department of Chemistry, Ataturk University, 25240 Erzurum, Turkey

2. 2Faculty of Arts and Sciences, Department of Chemistry, Erzincan University, 24100 Erzincan, Turkey

Abstract

AbstractA novel method for the production of singlet oxygen from H2O2 was developed. A combination of iodoarene (ArI), methyltrioxorhenium (MTO), and H2O2 in the presence of pyridine as the co-catalyst efficiently produced singlet molecular oxygen (1O2) under biphasic conditions. The existence of 1O2 was demonstrated by trapping experiments with aromatic dienes, 1,3-cyclodienes, and alkenes. The mechanism of 1O2 production from the iodoarene/MTO/35 % H2O2 system and the reaction scope was also discussed.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/pac-2013-0812/pdf

Reference28 articles.

1. de;Dong;Catal,2012

2. Oxidative De-aromatization ofpara-Alkyl Phenols intopara-Peroxyquinols andpara-Quinols Mediated by Oxone as a Source of Singlet Oxygen

3. a;Peters;Am Chem Soc Am Chem Soc Org Chem Nardello Tetrahedron,1972

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