Notizen: Sulfen-Einschiebung bei der Darstellung von π-C5H5(CO)3WS(O)2CH3 1? / Sulfene Insertion in the Synthesis of π-C5H5(CO)3WS(O)2CH3?

Author:

Lorenz Ingo-Peter1,Griesshammer Rainer1

Affiliation:

1. Institut für Anorganische Chemie der Universität Tübingen

Abstract

A new synthetic route for sulfinato complexes is reported: π-C5H5(CO)3WS(O)2CH3 can very easily be prepared from π-C5H5(CO)3WH, CH3SO2Cl and N(C2H5)3, a reaction in which sulfene (CH2=SO2) -insertion into metal-hydrogen-bonding may be involved.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Cited by 9 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Other 1,2-Insertion Reactions;Inorganic Reactions and Methods;2007-05-29

2. The coordination chemistry of iminooxosulphuranes;Journal of Organometallic Chemistry;1989-08

3. Oxidation of thiolate ligands in cyclopentadienyltungsten carbonyl complexes;Inorganic Chemistry;1987-09

4. Tungsten Compounds with η2–η8 Carbon Ligands;Comprehensive Organometallic Chemistry;1982

5. Sulfeninsertion und cis—trans-isomerie bei der synthese von [(C6H5)3P](CO)4Mn[S(O)2CH3];Journal of Organometallic Chemistry;1979-12

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