Affiliation:
1. Institut für Anorganische Chemie der Universität München Herrn Professor BIRKOFER zum 65. Geburtstag am 5. Juli 1976 gewidmet
Abstract
By reaction of carbon tetrachloride with lithium tris(trimethylsilyl)hydrazide and then with lithium butyl a compound with formula (Me3Si)2N2C is formed. From the way of preparation, spectroscopic investigations, and chemical reactions the substance is characterized as bis(trimethylsilyl)aminoisocyanide (3). 3 hydrolyzes, and does not react with oxygen. The compound combines with chlorine and bromine forming aminoisocyanide dihalides, and with carbon disulfide forming an adduct. At higher temperatures 3 isomerizes to bis(trimethylsilyl)carbodiimide (1).
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