Notizen: Gezielte Synthese von Sulfinato-O̲- und -S̲-Komplexen einiger Übergangsmetalle, XVI1 Sulfinato-S̲-Komplexe von Palladium(II) mit schwachen Donorliganden.

Abstract

The complexes Na[(RS(O)2)2PdClL] (L = CH3CN (2), (CH3)2CO (3), THF (4)), stable in solid state, are obtained by substitution of H2O by weak donor ligands from Na[(RS(O)2)2PdCl(OH2)] (1). Their special reactivity in solution is shown by the ready substitution of all ligands, RSO2⁻ included. The IR spectra are discussed.