Affiliation:
1. Institut für Organische Chemie der Universität Graz
Abstract
The combined action of orthoformate and aniline upon cyclohexanedione-1,3 yields anilinomethylene-cyclohexanedione-1,3, which react with cyanoacetate or malodinitrile in DMF in the presence of KOH to give ethyl-1-phenyl-2,5-dioxo-1,2,5,6,7,8-hexahydroquinoline-3-carboxylates (or -carbonitrils)
Cited by
25 articles.
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1. Photoluminescent Lanthanide(III) Complexes Based on 2-[((4-Chlorophenyl)amino)methylene]-5,5-dimethylcyclohexane-1,3-dione;Russian Journal of Coordination Chemistry;2024-04
2. SYNTHESIS, STRUCTURE, AND STUDY OF THE BIOLOGICAL ACTIVITY OF Co(II), Ni(II), AND Cu(II) COMPLEXES WITH AN ENAMINEDIONE DERIVATIVE;Journal of Structural Chemistry;2021-02
3. Synthesis, crystal structures, spectroscopic, and cytotoxicity study of Cu(II), Co(II), Ni(II) and Pd(II) complexes with 2-anilinomethylidene-5,5-dimethylcyclohexane-1,3-dione;Polyhedron;2020-03
4. Using Chou’s 5-Step Rule to Evaluate the Stability of Tautomers: Susceptibility of 2-[(Phenylimino)-methyl]-cyclohexane-1,3-diones to Tautomerization Based on the Calculated Gibbs Free Energies;Energies;2020-01-01
5. Cascade Two- and Three-Component Cyclization Reactions Using 1,2-Diamino-4-Phenylimidazole and Cyclohexane-1,3-Diones;Chemistry of Heterocyclic Compounds;2014-11-18