Affiliation:
1. Institut für Anorganische Chemie der RWTH Aachen
Abstract
In the temperature range from 54 to 75°Ca new modification of KNH2 was found, which crystallizes tetragonally a = 4.282 ± 0.003 Å, c = 6.182 ± 0.003 Å, and c/a = 1.444 (60°C), in P4/nmm - No. 129-, Z = 2,
2 K in 2c 0 1/2 z, z = 0.202(5),
2 N in 2c 0 1/2 z, z = 0.737(15). Its structure is of a deformed sodium chloride type.
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