Vergleich der Amino- und Hydroxy-Nachbargruppe bei Dehydrierungen.

Author:

Möhrle H.1,Kamper Chr.1,Feil R.1

Affiliation:

1. Institut für Pharmazie der Freien Universität Berlin

Abstract

The mercuric EDTA dehydrogenation of the isomeric 1,2- and 2,1-(phenyl-pyrrolidino)-ethanols yields with two electron removal the corresponding oxazolidines. The analogous 1,2- and 2,1-(amino-phenyl)pyrrolidines by double dehydrogenation produce the amidines resp. by subsequent hydrolysis the lactams. An explanation for the different course of the reaction is given

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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