Derivatives of cis-NPCl2(NSOCI)2 and (NPCl2)2NSOCl, V / Preparation of NPCl2(NSOPh)2 and (NPCl2)2NSOPh. Reactions of NPCl2(NSOPh)2 with Dimethylamine-Reference-Cited by-同舟云学术

Derivatives of cis-NPCl2(NSOCI)2 and (NPCl2)2NSOCl, V / Preparation of NPCl2(NSOPh)2 and (NPCl2)2NSOPh. Reactions of NPCl2(NSOPh)2 with Dimethylamine

Published:1976-09-01 Issue:9 Volume:31 Page:1216-1218
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Van Den Berg J. B.¹,De Ruiter B.¹,Van De Grampel J. C.¹

Affiliation:

1. Laboratorium voor Anorganische Chemie, Rijksuniversiteit Groningen, Zernikelaan, Groningen, The Netherlands

Abstract

Reaction of (NPCl2)2NSOCl or (NPCl2)2NSOF with benzene in the presence of AlCl3 yields (NPCl2)2NSOPh. By the same procedure two isomeric forms of NPCl2(NSOPh)2 can be obtained from cis-NPCl2(NSOCl)2. The phenylated products were characterized by IR, mass and 31P NMR spectra. Reactions of one of the isomers of NPCl2(NSOPh)2 with (CH3)2NH yield NPClN(CH3)2(NSOPh)2 (molar ratio 1:2) and NP[N(CH3)2]2(NSOPh)2 (molar ratio 1:6.8). The structures of the amino substituted derivatives were determined by means of 1H NMR measurements.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1976-0913/pdf

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1. Derivatives of cis-NPCl2(NSOCl)2 and (NPCl2)2NSOCl. Part VII. Isothiocyanato derivatives of (NPCl2)2NSOF, (NPCl2)2NSOPh and trans-NPCl2(NSOPh)2;Recueil des Travaux Chimiques des Pays-Bas;2010-09-02

2. Reactions of ferrocene-derived bis(hydroxymethyl) phosphine sulfides FcCH(R)P(S)(CH2OH)2 (R=H, CH3) with cyclic thionylphosphazenes: crystal structures of FcCH2P(S)(CH2O)2PN(NPCl2)[NS(O)Ph] and FcCH2P(S)(CH2O)2PN2P[N(Me)CH2]2[NS(O)Ph] (Fc=ferrocenyl);Journal of Organometallic Chemistry;2001-12

3. Attempted Generation of the Thionylphosphazene Cation [NSO(NPCl2)2]+: Novel Reactivity and the Discovery of an Ambient Temperature Ring-Opening Polymerization Route to Poly(thionylphosphazenes);Journal of the American Chemical Society;1998-03-20

4. FLUORINATED CYCLOTHIAPHOSPHAZENES: SYNTHESIS, STRUCTURE AND REACTIVITY;Phosphorus, Sulfur, and Silicon and the Related Elements;1996-08-01

5. Regioselective Substitution Reactions of Sulfur(VI)−Nitrogen−Phosphorus Rings: Reactions of the Halogenated Cyclic Thionylphosphazenes [NSOX(NPCl2)2] (X = Cl or F) with Oxygen-Based Nucleophiles;Inorganic Chemistry;1996-01-01