Affiliation:
1. Institut für Anorganische und Analytische Chemie der Technischen Universität Berlin
Abstract
Trimethylchlorosilane reacts with magnesium in hexamethylphosphortriamide yielding hexamethyldisilane. An organosilylmagnesium compound is proposed as reactive intermediate in this reaction. Further evidence for the existence of trimethylsilylmagnesium compounds could be obtained in the reaction of trimethylchlorosilane with highly reactive magnesium in tetrahydrofurane as solvent.
Cited by
11 articles.
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