Über die Darstellung von CH3C6H4S(O)2NCl2H+SbF- 6 und die Kristallstruktur von CH3C6H4S(O)2NCl2 / On the Synthesis of CH3C6H4S(O)2NCl2,H+SbF- 6 and the Crystal Structure of CH3C6H4S(O)2NCl2-Reference-Cited by-同舟云学术

Über die Darstellung von CH3C6H4S(O)2NCl2H+SbF- 6 und die Kristallstruktur von CH3C6H4S(O)2NCl2 / On the Synthesis of CH3C6H4S(O)2NCl2,H+SbF- 6 and the Crystal Structure of CH3C6H4S(O)2NCl2

Published:1997-01-01 Issue:1 Volume:52 Page:88-94
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Minkwitz Rolf¹,Garzarek Petra²,Preut Hans²

Affiliation:

1. Universität Dortmund, Fachbereich Chemie, Anorganische Chemie, Postfach 500500,D-44221 Dortmund

2. Universität Dortmund, Fachbereich Chemie. Anorganische Chemie, Postfach 500500,D-44221 Dortmund

Abstract

The crystal structure of CH3C6H4S(O)2NCl2 is reported. Crystals are monoclinic, space group P21/c, with a = 710.0(7), b = 1615.3(13), c = 867.2(7) pm, V = 988(2) pm3 and Z = 4. The reaction with HF/SbF5 yields CH3C6H4S(O)2NCl2H+SbF- 6 the first protonated dichloroamine salt, its vibrational -and NMR spectra are discussed

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1997-0118/pdf

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