Affiliation:
1. 1Anorganische Chemie II, U niversität Bayreuth, D-95440 Bayreuth, Germany
Abstract
The signs of coupling constants [ 1J(195Pt,13C) (> 0), 2J(195Pt,1H) (< 0), ∑2J (31P,13C)trans + 2J(31P,13C)cis (> 0) and ∑3J(31P,1H )trans +3J(31P,1H)cis (< 0)] in (ethene)bis(triphenylphosphane) platinum (0) (1) were determined by selective heteronuclear double and triple resonance experiments of the type 1H{31P}, 13C{1H,31P} and two-dimensional heteronuclear shift correlations (HETCOR) of the type 13C/1H, 195Pt/1H, and 31P/1H, either by observing the heteronucleus or 1H in the more sensitive inverse mode.
Cited by
7 articles.
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