1.3-Dithienium-and 1.3-Dithiolenium Salts, VI ,13C NMR Spectroscopic Investigations on 2-Substituted 1,3-Dithian-2-ylium Cations. Unusual γ-Effects

Author:

Kalinowski Hans-Otto1,Stahl Ingfried2

Affiliation:

1. Institut für Organische Chemie, Justus-Liebig-Universität, Heinrich-Buff-Ring 58, D-35392 Gießen

2. Bereich Organische Chemie des Fachbereichs 19 der Universität/Gesamthochschule Kassel, Heinrich-Plett-Straße 40, D-34132 Kassel

Abstract

Abstract The 13C NMR chemical shifts of 19 2-substituted 1,3-dithian-2-ylium-tetrafluorborates 1a-1s are discussed in comparison to known analogous 1,3-dithianes and 2-lithio-1,3-dithianes. The unusual γ-effects (up to 9 ppm), which can also observed in other six-membered ring systems, are explained by the electric field effect (σ-polarisation effect). The electron density distribution can be estimated qualitatively by comparison with the 1,3-dioxan-2-ylium-and cyclohexylcations.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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