Author:
Ünlü Ayşe Ezgi,Arıkaya Azime,Takaç Serpil
Abstract
Abstract
Deep eutectic solvents (DESs) exhibit numerous advantages over conventional ones used in several chemical and biochemical processes. Besides addressing most of the principles of green chemistry, DESs can also act as catalyst depending on their nature. The use of DESs as acid catalyst has several advantages such as utilization at stoichiometric amount, non-toxicity, possibility of the recovery, similar or higher catalytic effect than the acid itself alone, the recyclability and reusability without a significant loss of activity. In this mini-review, the state- of-the-art in the use of DESs as catalyst is presented. The DESs, which show Lewis type acidity, Brønsted type acidity and other types of catalytic influence in various types of reactions including esterification, organic synthesis, glycolysis and depolymerisation are presented and their roles in the reactions are discussed.
Subject
Health, Toxicology and Mutagenesis,Industrial and Manufacturing Engineering,Fuel Technology,Renewable Energy, Sustainability and the Environment,General Chemical Engineering,Environmental Chemistry
Reference206 articles.
1. A Synthetic Study on the Preparation of Triarylmethanes;Dye. Pigment,1994
2. Incorporation of biotinylated manganese-salen complexes into streptavidin: New artificial metalloenzymes for enantioselective sulfoxidation;J. Organomet. Chem,2009
3. Perchloric acid adsorbed on silica gel as a new, highly efficient, and versatile catalyst for acetylation of phenols, thiols, alcohols, and amines;Chem. Commun,2003
4. Promises in direct conversion of cellulose and lignocellulosic biomass to chemicals and fuels: Combined solvent-nanocatalysis approach for biorefinary;Biomass and Bioenergy,2014
5. Hydrothermal liquefaction of de-oiled Jatropha curcas cake using Deep Eutectic Solvents (DESs) as catalysts and co-solvents;Bioresour. Technol,2016
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