A solid-state <sup>171</sup>Yb NMR-spectroscopic characterization of selected divalent ytterbium intermetallics-Reference-Cited by-同舟云学术

A solid-state ¹⁷¹Yb NMR-spectroscopic characterization of selected divalent ytterbium intermetallics

Published:2024-01-01 Issue:1 Volume:79 Page:13-19
ISSN:0932-0776
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Gerdes Josef Maximilian¹,Schumacher Lars²,Hansen Michael Ryan¹,Pöttgen Rainer²

Affiliation:

1. Institut für Physikalische Chemie, Universität Münster , Corrensstrasse 30, 48149 Münster , Germany

2. Institut für Anorganische und Analytische Chemie, Universität Münster , Corrensstrasse 30, 48149 Münster , Germany

Abstract

Abstract The intermetallic ytterbium compounds YbZnSn, YbPdSn2, YbAuIn2 and their calcium-substituted counterparts Yb0.5Ca0.5ZnSn, Yb0.5Ca0.5PdSn2 and Yb0.5Ca0.5AuIn2 were synthesized by reaction of the elements in sealed tantalum tubes in an induction furnace. The samples were characterized by X-ray powder diffraction. Their static, temperature-dependent solid-state 171Yb NMR spectra exhibit strong positive Knight shifts without any significant temperature dependence. The resonance shifts including anisotropy parameters for the ternary compounds have been determined.

Publisher

Walter de Gruyter GmbH

Link

https://www.degruyter.com/document/doi/10.1515/znb-2023-0070/pdf

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