[Me3N(C6H3(CF3)2)][BF4] and [Me3N(C6H3(CH3)2)][BF4], as potential synthons for non-covalent supramolecular assembly-Reference-Cited by-同舟云学术

[Me₃N(C₆H₃(CF₃)₂)][BF₄] and [Me₃N(C₆H₃(CH₃)₂)][BF₄], as potential synthons for non-covalent supramolecular assembly

Published:2024-01-01 Issue:1 Volume:79 Page:57-61
ISSN:0932-0776
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Schmid Jonas R.¹^ORCID,Wiesner Anja¹^ORCID,Voßnacker Patrick¹^ORCID,Jansen Martin²^ORCID,Riedel Sebastian¹^ORCID

Affiliation:

1. Anorganische Chemie , Institut für Chemie und Biochemie, Freie Universität Berlin , Fabeckstraße 34/36, 14195 Berlin , Germany

2. Max-Planck-Institut für Festkörperforschung , Heisenbergstraße 1, 70569 Stuttgart , Germany

Abstract

Abstract The compounds [Me3N(C6H3(CF3)2)][BF4] and [Me3N(C6H3(CH3)2)][BF4] were synthesized from commercially available starting materials and fully characterized by single-crystal X-ray diffraction, NMR, IR and Raman spectroscopy, as well as mass spectrometry. Both ammonium cations show potential for applications in crystal engineering due to their structure directing properties in the solid state.

Publisher

Walter de Gruyter GmbH

Link

https://www.degruyter.com/document/doi/10.1515/znb-2023-0095/pdf

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