Electrical Conductivity of Molten Binary Ndbr3 – Alkali Bromide Mixtures

Author:

Gadzuric S.1,Ingier-Stocka E.2,Rycerz L.2,Gaune-Escard M.3

Affiliation:

1. Faculty of Natural Science, Department of Chemistry, University of Novi Sad, Trg D. Obradovica 3, 21000 Novi Sad, Serbia & Montenegro

2. Institute of Inorganic Chemistry and Metallurgy of Rare Elements, University of Technology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland

3. Ecole Polytechnique, Mecanique Energetique, Technopole de Chateau Gombert, 5 rue Enrico Fermi, 13453 Marseille Cedex 13, France

Abstract

Electrical conductivity of liquid binary NdBr3 - alkali metal bromide mixtures was measured as a function of temperature over the whole composition range. Prior to these measurements, NdBr3 and alkali bromides were reinvestigated: a new assessment of literature data was made because of the discrepancy with reference values on NdBr3, LiBr and CsBr. The classical Arrhenius equation describes well our electrical conductivity data for mixtures. These results are discussed in terms of complex formation in the melts.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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