Studies of the Zero-Field Splitting for Mn2+ In 6H-RbMgF3 Crystal-Reference-Cited by-同舟云学术

Studies of the Zero-Field Splitting for Mn2+ In 6H-RbMgF3 Crystal

Published:2004-12-01 Issue:12 Volume:59 Page:961-963
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:en
Short-container-title:

Author:

Zheng Wen-Chen¹²,Mei Yang³,Wu Xiao-Xuan⁴⁵²,Zhou Qing³

Affiliation:

1. a Department of Material Science, Sichuan University, Chengdu 610064, P. R. China

2. International Centre for Materials Physics, Chinese Academy of Sciences, Shenyang 110016, P. R. China

3. Department of Material Science, Sichuan University, Chengdu 610064, P. R. China.

4. Department of Material Science, Sichuan University, Chengdu 610064, P. R. China

5. Department of Physics, Civil Aviation Flying Institute of China, Guanghan 618307, P. R. China

Abstract

By using the spin-orbit coupling mechanism and the empirical superposition model, the zero-field splittings D of Mn2+ ions on both Mg2+ sites in hexagonal 6H-RbMgF3 crystal are calculated from the structural data of both Mg2+ sites. The calculated results of both methods confirm the suggestion that Mn2+ in 6H-RbMgF3 occupies the Mg2+ (I) site (which has D3d site symmetry) and the zero-field splitting D of 6H-RbMgF3: Mn2+ is explained reasonably.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-2004-1213/pdf

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