The 35Cl NQR Temperature Dependence of Hexa- and Octachlorocyclophosphazene

Author:

Koukoulas Alexander A1,Whitehead M. A.2

Affiliation:

1. 1Pulp and Paper Research Institute of Canada, 570 St. John's Rd., Pointe Claire, PQ, Canada H9R 3J9

2. 2Department of Chemistry, McGill University, Montreal, PQ, Canada, H3A 2K6

Abstract

AbstractThe 35Cl NQR temperature dependence in (PNCl2)3 and (PNCl2)4 was measured between 77 K and 293 K. The dependence in both compounds was smoothly varying. A sudden decrease in T2* near 112 K indicated the presence of a strong broadening mechanism in (PNCl2)3. The nature of this mechanism is interpreted in terms of the Cl spin-lattice relaxation

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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