Phase Transition in Cesium Enneabromodibismuthate(III), Cs3Bi2Br9 ; an 81Br and 209Bi NQR Study

Author:

Terao Hiromitsu1,Ishihara Hideta2,Okuda Tsutomu3,Yamada Koji3,Weiss Alarich4

Affiliation:

1. 1Faculty of Integrated Arts and Sciences, Tokushima University, Minamijosanjima-cho, Tokushima 770, Japan

2. 2Department of Chemistry, Faculty of Education, Saga University, Honjo-machi 1, Saga 840, Japan

3. 3Department of Chemistry, Faculty of Science, Hiroshima University, Kagamiyama, Higashihiroshima 724, Japan

4. 4Institut für Physikalische Chemie, Physikalische Chemie III, Technische Hochschule Darmstadt, Petersenstr. 20, D-6100 Darmstadt, Germany

Abstract

The 81Br and 209Bi NQR spectra of Cs3Bi2Br9 have been studied over a wide temperature range (81Br-NQR: 77 ≤ T/K ≤ 383; 209Bi-NQR: 77 ≤ T/K ≤ 310). Therefrom a phase transition in the compounds is found which is probably of second order.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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