Hydrogenation of nitriles and imines for hydrogen storage

Abstract

Abstract This review focuses on the selective catalytic hydrogenation of nitriles to primary amines both homogeneously and heterogeneously with transition metal-based catalysts in the view of nitriles as hydrogen carriers. Nitriles can be reduced with two equivalents of H2 to primary amines, thus having a great potential to serve as liquid organic hydrogen carriers (LOHCs) for hydrogen storage. Imines are intermediates in the hydrogenation of nitriles to amines, thus they can also serve as potential LOHCs, however with a lower hydrogen storage capacity (HSC).