Recent advances in reactions promoted by amino acids and oligopeptides

Author:

Triandafillidi Ierasia1,Voutyritsa Errika1,Kokotos Christoforos G.1

Affiliation:

1. Laboratory of Organic Chemistry, Department of Chemistry , National and Kapodistrian University of Athens , Panepistimiopolis, Athens 15771, Greece

Abstract

Abstract During the last 20 years, Organocatalysis has become one of the major fields of Catalysis. Herein, we provide a recent overview on reactions where the use of amino acids and peptides as the organocatalysts was employed. All aspects regarding aldol reactions, Michael reactions, epoxidation, Henry reactions and many others that are crucial for the reaction conditions and reaction mechanisms are discussed.

Publisher

Walter de Gruyter GmbH

Subject

General Physics and Astronomy,General Materials Science,General Chemistry

Reference234 articles.

1. For selected books on asymmetric organocatalysis, see: (a) Berkessel A, Groger H. Metal free organic catalysis in asymmetric synthesis, Wiley-VCH:Weinheim, 2004; (b) Berkessel A, Groger H. Asymmetric organocatalysis – from biomimetic concepts to applications in asymmetric synthesis. Weinheim: Wiley-VCH, 2005; (c) Dalko PI. Enantioselective organocatalysis. Weinheim: Wiley-VCH, 2007; (d) List B. Asymmetric organocatalysis. Berlin, Heidelberg: Springer, 2009; (e) Pellissier H. Recent developments in asymmetric organocatalysis. Cambridge: RSC Publishing, 2012; (f) Dalko PI. Comprehensive stereoselective organocatalysis, vols 1–3, Weinheim: Wiley-VCH, 2013; (g) Rios Torres R. Stereoselective organocatalysis-bond formation methodologies and activation modes. Hoboken, New Jersey: Wiley, 2013. For reviews, see: (h) Dalko PI, Moisan L. In the golden age of organocatalysis. Angew Chem Int Ed. 2004;43:5138–75; (i) Mukherjee S, Yang JW, Hoffmann S, List B. Asymmetric enamine catalysis. Chem Rev. 2007;107:5471–569; (j) Dondoni A, Massi A. Asymmetric organocatalysis: from infancy to adolescence. Angew Chem Int Ed. 2008;47:4638–60; (k) Melchiorre P, Marigo M, Carlone A, Bartoli G. Asymmetric aminocatalysis-gold rush in organic chemistry. Angew Chem Int Ed. 2008;47:6138–71.

2. (a) Ahrendt KA, Borths CJ, MacMillan DW. New strategies for organic catalysis: the first highly enantioselective organocatalytic Diels-Alder reaction. J Am Chem Soc. 2000;122:4243-4

3. (b) MacMillan DWC. The advent and development of organocatalysis. Nature. 2008;455:304-8.

4. For selected reviews, see: (a) Wang YB, Tan B. Construction of axially chiral compounds via asymmetric organocatalysis. Acc Chem Res. 2018, 51, 534-47

5. (b) Zhu Y, Wang Q, Cornwall RG, Shi Y. Organocatalytic asymmetric epoxidation and aziridination of olefins and their synthetic applications. Chem Rev. 2014;114:8199-256

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3