Vitamin-Synthesen mit Carben-Komplexen, III [1]. Stereospezifische Synthese von Alkenylcarben-Komplexen des Chroms / Vitamin Syntheses via Carbene Complexes, III [1]. Stereospecific Synthesis of Alkenylcarbene Chromium Complexes-Reference-Cited by-同舟云学术

Vitamin-Synthesen mit Carben-Komplexen, III [1]. Stereospezifische Synthese von Alkenylcarben-Komplexen des Chroms / Vitamin Syntheses via Carbene Complexes, III [1]. Stereospecific Synthesis of Alkenylcarbene Chromium Complexes

Published:1983-11-01 Issue:11 Volume:38 Page:1351-1356
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Dötz Karl Heinz¹,Kuhn Werner¹,Ackermann Klaus¹

Affiliation:

1. Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstraße 4, D-8046 Garching

Abstract

Abstract Addition of lithioalkenes to hexacarbonylchromium followed by alkylation with trimethyloxonium tetrafluoroborate provides a stereospecific route to pentacarbonyl-[alkenyl(methoxy)carbene]chromium complexes. For the E-butenylcarbene complex an approximately orthogonal dihedral angle between the carbene and the alkene plane is established by X-ray analysis.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1983-1106/pdf

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