Kristallstruktur und Schwingungsspektren des Thalliumhexathiometadiphosphates Tl2P2S6 / Crystal Structure and Vibrational Spectra of Tl2P2S6-Reference-Cited by-同舟云学术

Kristallstruktur und Schwingungsspektren des Thalliumhexathiometadiphosphates Tl2P2S6 / Crystal Structure and Vibrational Spectra of Tl2P2S6

Published:1983-12-01 Issue:12 Volume:38 Page:1575-1580
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Wibbelmann Claus¹²,Brockner Wolfgang¹,Eisenmann Brigitte³,Schäfer Herbert³

Affiliation:

1. Institut für Anorganische Chemie, Technische Universität Clausthal, Paul-Ernst-Straße 4, D-3392 Clausthal-Zellerfeld

2. Institute of Inorganic Chemistry. The Technical University of Norway, N-7034 Trondheim-NTH, Norway.

3. Abteilung II für Anorganische Chemie im Eduard-Zintl-Institut der Technischen Hochschule Darmstadt, Hochschulstraße 4, D-6100 Darmstadt

Abstract

Tl2P2S6 crystallizes in the orthorhombic system, space group Immm, Z = 2 with the lattice constants a = 793.2(4) pm, b = 689.2(4) pm, c = 901.9(5) pm. In the structure there are discrete P2S6 2- -anions. The P2S6 2- -ion was found to be a hexa-thiometadiphosphate group where the two P atoms are linked by two S bridges. Far infrared, infrared and Raman spectra of this compound have been recorded. The observed frequencies are assigned on the basis of P2S6 2- units with D2h symmetry in analogy to the isoelectronic Al2Cl6

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1983-1208/pdf

Cited by 30 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis, crystal structure, optical bandgap, and electronic structure of Cs2FeP2S6;Solid State Sciences;2022-06

2. The First Quinary Rare Earth Thiophosphates: Cs5Ln3X3(P2S6)2(PS4) (Ln= La, Ce,X= Br, Cl) and the Quasi-Quaternary Cs10Y4Cl10(P2S6)3;Zeitschrift für anorganische und allgemeine Chemie;2017-11-15

3. Synthesis and Characterization of Copper Hexathiometadiphosphate Cu2 P2 S6;Zeitschrift für anorganische und allgemeine Chemie;2016-02-29

4. Synthesis and Structural Characterization of the Alkali Thiophosphates Na2P2S6, Na4P2S6, K4P2S6, and Rb4P2S6;Zeitschrift für anorganische und allgemeine Chemie;2014-01-31

5. Structural investigations of yNa2S+(1−y)PS5/2 glasses using Raman and infrared spectroscopies;Journal of Non-Crystalline Solids;2012-12