Affiliation:
1. Institut für Anorganische Chemie der Universität München, Meiserstraße 1, D-8000 München 2
Abstract
Abstract
cis-Dichlorobis(chlorodiphenylphosphine)palladium-and platinum(II) react with N-alkyl-α-amino acid esters to give the complexes MCl2[Ph2PN(R)C(H)(R')CO2Me]2 (M = Pd, Pt; R = CH2Ph, i-C3H7; R' = CH3, CH2Ph). With lysine ester dimeric, bis(chelate) complexes
(M = Pd, Pt; R = CH3, C2H5)
have been isolated. The reaction of cis-MCl2(PPh2Cl)2 with cysteine and serine methylester affords the complexes MCl2[Ph2P(X)CH2C(H)(NH2)CO2CH3]2 (M = Pd, Pt; X = O, S).
Cited by
7 articles.
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