Affiliation:
1. Lehrstuhl B für Anorganische Chemie der Technischen Universität, Pockelsstraße 4, D-3300 Braunschweig
Abstract
Abstract
Alkyldifluorophosphites, ROPF2 (R = p-substituted benzyl group, neopentyl, 1-adamantyl) have been obtained by a new method, involving reaction of the appropriate alkyl trimethylsilylether, ROSiMe3 with chlorodifluorophosphine, PF2Cl. Reactions of these difluorophosphites with platinum(II) complexes of the type [L2PtCl2] (L = PEt3, PPh3) led to products such as trans-[L2PtCl(POF2)] and {[p-XC6H4CH2PPh3]+}2[Pt(POF2)4]2-, (X = H, Me, Cl, NO2). The ease of carbon-oxygen cleavage in ROPF2 is characteristically related to the nature of the leaving group, R.
Cited by
9 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Umsetzungen von Allyldichlorphosphit und Allyldifluorphosphit mit einigen Verbindungen von �bergangsmetallen; Darstellung und spektroskopische Untersuchung von Allyldichlor- bzw. Allyldifluorphosphit-Carbonyl-Metall(0)-Koordinationsverbindungen (Metall?Cr, Mo, W, Fe);Zeitschrift f�r anorganische und allgemeine Chemie;1997-08
2. A New Synthesis of
P
‐Substituted 2,3‐Dihydro‐1,3‐dimethyl‐1,3,2δ
3
‐benzodiazaphosphorin‐4(1
H
)‐ones and Alkylaminodifluorophosphanes with Chlorodifluorophosphane. — Synthesis and Structure of {
cis
‐Bis[bis(2‐chloroethyl)aminodifluorophosphane]dichloro}platinum(II);Chemische Berichte;1995-07
3. Synthesis and NMR studies of difluorophosphine-substituted ureas;Polyhedron;1989-01
4. Coordination Chemistry reviews;Coordination Chemistry Reviews;1988-09
5. Preparation of ortho-substituted aryldifluorophosphines, 2-XC6H4PF2 (X = MeO or Me2N), and some of their derivatives. X-ray crystal structure determination of (2-MeOC6H4P)4 and of the platinum complex, Cl2Pt(2-MeOC6H4PF2)2;Polyhedron;1987-01