Affiliation:
1. Institut für anorganische Chemie der Universität Stuttgart, Pfaffenwaldring 55, D-7000 Stuttgart 80
Abstract
Abstract
d,h-μ-Dimethylphosphinato-e-μ-methoxo-f-μ-oxo-bis[trichloroantimony(V)] (1) and bis-(μ-dimethylphosphinato)-μ-oxo-bis[trichloroantimony(V)] (2) were prepared by reaction of bis(μ-dimethylphosphinato-0,0′)-bis[tetrachloroantimony(V)] with antimony(V)-chlo-ride/water 1:1 and antimony(V)-chloride/water/methanol 1:1:1, resp. The crystal and molecular structure of 2 was determined by X-ray analysis. The vibrational spectra of 1 and 2 are discussed. The mass spectrum of 2 was measured and the fragmentation classified.
Cited by
18 articles.
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