Affiliation:
1. Tomas Bata University in Zlin, Faculty of Technology, TGM 275, 762 72Zlin, Czech Republic
Abstract
AbstractThe temperature dependent flow properties of highly filled polymer compounds intended for production of hard-metal parts by powder injection moulding (PIM) technology were studied. The pure binder based on polyethylene, ethylene and butyl acrylate block copolymer and paraffin, and its compounds with hard-metal carbide powder (up to 55 vol. %) were prepared by melt mixing at 180˚C. The flow properties were investigated at the temperature range from 140˚C to 200˚C using capillary rheometer operating flow at a constant piston speed. The measure of temperature sensitivity of PIM compounds, activation energy of shear flow, decreases with powder loading and shear rate. The Arrhenius relation for these materials is only valid in the stable flow region. At the temperatures above 170˚C the compounds filled with 45 vol. % carbide powder and higher exhibit an unstable flow of pressure oscillations type at the shear rates above 103 s-1. The onset of pressure oscillations is strongly affected by temperature. The relation between critical shear stress for the onset of pressure oscillations and temperature is non-linear.
Subject
Condensed Matter Physics,General Materials Science
Cited by
9 articles.
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