Affiliation:
1. Institute of Applied Radiation Chemistry, Technical University, Wróblewskiego 15, 93-590 Lódź, Poland
Abstract
The conductance of Nal in acetonitrile-water mixtures was measured at 25.000 ± 0.001 °C for the whole composition range of the mixed solvent, the salt molarity ranging from 5 · 10-5 to 1 · 10-2 . Using the Fuoss-Hsia equation with the Fenandez-Prini parameters, the association constants were computed for several values of the ion-ion distances. The influence of the mixed solvent composition on the ionic association is discussed. An arranging effect of the sodium ions, postulated previously, is confirmed.
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics
Cited by
5 articles.
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