Notizen: Cross Polarization in Electron Nuclear Double Resonance by Satisfying the Hartmann-Hahn Condition

Author:

Brunner H1,Fritsch R. H.2,Hausser K. H.1

Affiliation:

1. Max-Planck-Institut, Heidelberg

2. Bruker-Analytische Meßtechnik, D -7512 Forchheim

Abstract

The polarization of electronic spins S is transferred to nuclear spins I by cross relaxation in an electron nuclear double resonance experiment. The cross relaxation becomes very efficient with a time constant Tcr of about 0.5 microseconds if the Hartmann-Hahn condition is satisfied for electronic spins S spin-lock ed to the microwave field B1,S in the rotating frame and for proton spins / in the static magnetic field B0.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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