Affiliation:
1. N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences , Moscow , Russia
Abstract
Abstract
1,2-trans-diiodo-ethene (C2H2I2) – is an overlooked halogen bond donor, which demonstrate the distinct similarity of the geometry and directionality of I···I halogen bonds around the iodine atoms in its native and CpMn(CO)2(C2H2I2) π-complex crystals. Distortion of the planar geometry of C2H2I2 upon the π-coordination result the distortion of the native planar layered geometry of C2H2I2, so that [CpMn(CO)2](π-C2H2I2) features more complex I···I XB assisted 3D network. Unusual structural parallels between the native C2H2I2 crystals and solid iodine are discussed.
Funder
Russian Scientific Foundation
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science
Cited by
13 articles.
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