NiAs-derived cyanamide (carbodiimide) structures – a group-theoretical view-Reference-Cited by-同舟云学术

NiAs-derived cyanamide (carbodiimide) structures – a group-theoretical view

Published:2023-01-26 Issue:0 Volume:0 Page:
ISSN:2194-4946
Container-title:Zeitschrift für Kristallographie - Crystalline Materials
language:en
Short-container-title:

Author:

Pöttgen Rainer¹,Corkett Alex J.²,Dronskowski Richard³⁴

Affiliation:

1. Institut für Anorganische und Analytische Chemie , Universität Münster , Corrensstrasse 30 , 48149 Münster , Germany

2. Institute of Inorganic Chemistry , RWTH Aachen University , 52056 Aachen , Germany

3. Chair of Solid-State and Quantum Chemistry , Institute of Inorganic Chemistry, RWTH Aachen University , 52056 Aachen , Germany

4. Hoffmann Institute of Advanced Materials , Shenzhen Polytechnic , 7098 Liuxian Blvd , Nanshan District , Shenzhen , China

Abstract

Abstract The cyanamide and carbodiimide anions are complex nitrogen-derived one-dimensional species of the type NCN2− (hence, resembling O2− but more covalently bonding) that form a huge number of salt-like phases with a variety of metal cations stemming from the whole Periodic Table. Depending on the coloring (binary, ternary and quaternary salts are known), the cationic size and charge as well as covalent contributions, different distortion (tilting in particular) and/or vacancy ordering variants of cyanamides/carbodiimides occur. Herein we summarize those cyanamide/carbodiimide structures that derive from the aristotype NiAs. The crystal chemistry is discussed on the basis of group-subgroup schemes (Bärnighausen trees).

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Link

https://www.degruyter.com/document/doi/10.1515/zkri-2022-0062/pdf

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