An asymmetric mononuclear cobalt(II) compound derived from 3-bromo-pyridine-2,6-dicarboxylic acid involving in-situ hydrothermal decarboxylation: structure, magnetic property and Hirshfeld surface analysis
Author:
Li Jun-Xia1, Ge Shuai2, Lu Yi-Jing2, Xu Xiao-Jie2, Liu Chang2, Li Shi-Hui1
Affiliation:
1. Henan Key Laboratory of Function-Oriented Porous Materials , College of Chemistry and Chemical Engineering , Luoyang Normal University , Luoyang , Henan Province , 471934 , P. R. China 2. College of Chemistry and Chemical Engineering , Luoyang Normal University , Luoyang , Henan Province , 471934 , P. R. China
Abstract
Abstract
A new cobalt(II) compound with the formula [Co(5-Br-pyc)(2,2′-bipy)(H2O)(Cl)]·2H2O (1·H2O) (5-Br-Hpyc = 5-bromo-pyridine-2-carboxylic acid, 2,2′-bipy = 2,2′-bipyridine) has been hydrothermally synthesized and well characterized. The X-ray single-crystal diffraction analysis showed that 1⋅2H2O has crystallizes in the monoclinic system, space group P21/c (no. 14). The Co(II) center was octahedrally bonded by one bidentate chelate 5-Br-pyc anion and one 2,2′-bipy, one water molecule as well as one chloride anion to form the mononuclear structure of 1⋅2H2O. Complex 1⋅2H2O forms a 3D network through abundant O–H⋅⋅⋅O hydrogen bonds and π⋅⋅⋅π stacking interactions. Notably, the 5-Br-Hpyc ligand was in situ generated by decarboxylation of the 3-bromo-pyridine-2,6-dicarboxylic acid (3-Br-H2pydc) precursor selectively on 2-position under hydrothermal conditions. The magnetic properties, the Hirshfeld surface structure and the synthetic process for 1⋅2H2O have been carefully described and discussed.
Funder
Key scientific research projects in colleges Universities of Henan province
Publisher
Walter de Gruyter GmbH
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science
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