Crown ether complexes as a possible template for hybrid organic–inorganic borates
Author:
Yukhno Valentina A.1, Charkin Dmitri O.23, Banaru Alexander M.23, Manelis Lev S.23, Gosteva Alevtina N.4, Volkov Sergey N.13, Aksenov Sergey M.3, Bubnova Rimma S.1
Affiliation:
1. Grebenshchikov Institute of Silicate Chemistry , Makarov Emb. 2 , St. Petersburg , 199034 , Russia 2. Department of Chemistry , Lomonosov Moscow State University , Moscow , 119991 , Russia 3. Laboratory of Arctic Mineralogy and Material Sciences, Kola Science Centre , Russian Academy of Sciences , Apatity , 184209 , Russia 4. I.V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Science Center , Russian Academy of Sciences , 184209 , Apatity , Russia
Abstract
Abstract
Crystals of the first new organo–inorganic hybrid borate based on potassium crown ether complex, [K(C12H24O6)B5O6(OH)4](H2O) (1), have been produced from aqueous solutions and characterized by single-crystal X-ray diffraction. 1 crystalizes is orthorhombic system, Pnma, a = 10.1684(3) Å, b = 11.6289(3) Å, c = 21.2247(6) Å, V = 2509.76(12) Å3, R
obs = 0.059. The structure of 1 consists of molecular [K(C12H24O6)B5O6(OH)4]0 complexes, common for crown ether complexes but yet not among borates, with a very rare monodentate coordination of the common pentaborate anion(1-). The molecular complexes are linked into weak chains via hydrogen bonding to outer-sphere water molecules. Hirshfeld surfaces analysis and complexity measurement of 1 were performed. Perspectives of borate structures containing crown ether complexes as templates are briefly outlined.
Funder
Russian Science Foundation Ministry of Science and Higher Education of the Russian Federation Institute of Silicate Chemistry Laboratory of Arctic Mineralogy and Material Sciences, Kola Science Centre
Publisher
Walter de Gruyter GmbH
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science
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