SmPt2In2 – a new ternary indide with a Pt–In polyanionic framework-Reference-Cited by-同舟云学术

SmPt2In2 – a new ternary indide with a Pt–In polyanionic framework

Published:2021-06-01 Issue:5-7 Volume:236 Page:155-162
ISSN:2196-7105
Container-title:Zeitschrift für Kristallographie - Crystalline Materials
language:en
Short-container-title:

Author:

Zaremba Nazar¹²,Muts Ihor²³,Pavlyuk Volodymyr²⁴,Hlukhyy Viktor¹,Pöttgen Rainer³,Kaczorowski Dariusz⁵,Zaremba Vasyl²

Affiliation:

1. Department of Chemistry , Technische Universität München , Lichtenbergstrasse 4 , 85747 Garching , Germany

2. Department of Inorganic Chemistry , Ivan Franko National University of Lviv , Kyryla and Mefodiya Street 6 , 79005 Lviv , Ukraine

3. Institut für Anorganische und Analytische Chemie, Universität Münster , Corrensstrasse 30 , 48149 Münster , Germany

4. Institute of Chemistry, Częstochowa Jan Długosz University in Częstochowa , al. Armii Krajowej 13/15 , 42200 Częstochowa , Poland

5. Institute of Low Temperature and Structure Research, Polish Academy of Sciences , ul. Okólna 2 , 50-422 Wroclaw , Poland

Abstract

Abstract Single crystals of a new samarium platinum indide have been synthesized in a high-frequency furnace under flowing argon atmosphere. The crystal structure of SmPt2In2 was determined from single-crystal X-ray data (R1 = 0.0416 for 1049 F values and 63 variables). It belongs to the CePt2In2 structure type with the following crystallographic parameters: P21/m, mP20, Z = 4, a = 10.0561(8), b = 4.4214(2), c = 10.1946(8) Å, β = 116.492(5)°, V = 405.68(5) Å3. Physical properties were studied and the crystal chemical discussion is supported by electronic structure calculations.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Link

https://www.degruyter.com/document/doi/10.1515/zkri-2021-2028/pdf

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