The ternary phase Li8SbxSn3-x with 0.3 ≤ x ≤ 1.0-Reference-Cited by-同舟云学术

The ternary phase Li8SbxSn3-x with 0.3 ≤ x ≤ 1.0

Published:2020-06-03 Issue:6-7 Volume:235 Page:183-192
ISSN:2196-7105
Container-title:Zeitschrift für Kristallographie - Crystalline Materials
language:en
Short-container-title:

Author:

Berger Patric¹,Schmetterer Clemens²,Silvia Effenberger Herta³,Flandorfer Hans¹

Affiliation:

1. Institute of Inorganic Chemistry – functional Materials , University of Vienna , Faculty of Chemistry , Althanstraße 14 (UZAII) , 1090 Vienna , Austria

2. Institute of Physical Chemistry , University of Vienna , Faculty of Chemistry , Waehringerstraße 42 , 1090 Vienna , Austria

3. Institute of Mineralogy and Crystallography , University of Vienna , Faculty of Geosciences, Geography and Astronomy , Althanstraße 14 (UZAII) , 1090 Vienna , Austria

Abstract

Abstract In the frame of the studies on the phase relations in the ternary system Li–Sb–Sn at 300 °C the new ternary phase Li8SbxSn3-x (0.3 ≤ x ≤ 1.0) was synthesized and characterized predominantly by single crystal and powder X-ray diffraction. The title compound crystallizes trigonally in the space group R

3 ‾

$‾{3}$

m (no. 166), the lattice parameters are a = 4.6962(11) Å and c = 31.536(6) Å. The crystal structure of Li8SbxSn3-x is described in the present paper. In addition, the stereochemical and topological relations to the phases with similar composition, namely Li13Sn5, Li5Sn2 as well as cubic Li3Sb, besides native Li are discussed.

Funder

DFG

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Link

https://www.degruyter.com/document/doi/10.1515/zkri-2020-0020/pdf

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