Transition to Semiconducting Characteristics in Liquid Alkalimetal-Antimony-Alloys

Author:

Redslob H.1,Steinleitner G.1,Freyland W.1

Affiliation:

1. Fachbereich Physikalische Chemie der Philipps-Universität Marburg

Abstract

Abstract The paper reports new measurements of the electrical conductivity, thermoelectric power, magnetic susceptibility, and molar volume of liquid Cs-Sb alloys and, partly, Na-Sb and K-Sb alloys. From the temperature and composition dependence of the electronic properties it is concluded that typical semiconducting behavior similar to liquid chalgogen based alloy semiconductors exists over a wide composition range. The change in bonding for 0.25≦XSb≦0.5 is qualitatively discussed and it is found that these liquid alloys are not essentially ionic in character.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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