NOTIZEN: Darstellung und Kristallstruktur von Rb6Cl4O / Preparation and Crystal Structure of Rb6Cl4O

Author:

Feldmann Claus1,Jansen Martin2

Affiliation:

1. Max-Planck-Institut für Festkörperforschung, Heisenbergstr. 1, D-70569 Stuttgart

2. Institut für Anorganische Chemie der Universität, Gerhard-Domagk-Str. 1, D-53121 Bonn

Abstract

The preparation and crystal structure of Rb6Cl4O (hexagonal, a = 12,621(4), c = 15,847(4) Å) are reported. The compound crystallizes in the anti-K4CdCl6 type of structure, which is closely related to the perovskites. Rb6Cl4O is the first 4:1 compound in pseudo-binary systems MX/M2O (M = alkali metal; X = halide, Au-, CN-, NO2 - ).

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Cited by 4 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Structural diversity and complexity of antiperovskites;Coordination Chemistry Reviews;2024-01

2. Synthesis, Structure and Electronic Properties of Three Tin Oxide Halides;European Journal of Inorganic Chemistry;2020-12-17

3. Li5OCl3and Li3OCl: Two Remarkably Different Lithium Oxide Chlorides;Zeitschrift für anorganische und allgemeine Chemie;2012-08-20

4. ChemInform Abstract: Preparation and Crystal Structure of Rb6Cl4O.;ChemInform;2010-08-04

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